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December 20, 2011 - Agrochemicals

Product Name Mancozeb
CAS No. 8018-1-7
Categories Fungicides
Chemical Structure NOMENCLATURE
Common name: mancozeb; mancozébe; manzeb
IUPAC name: manganese ethylenebis(dithiocarbama te) (polymeric) complex with zinc salt
Chemical Abstracts name: [[1, 2-ethanediylbis[carbamodi thioato]](2-)]manganese mixture with [[1, 2-ethanediylbis[carbamodi thioato]](2-)]zinc
CAS RN: [8018-01-7] (formerly [8065-67-6]); [8018-01-7] is also applied to other mixed manganese and zinc ethylenebis(dithiocarbama te) complexes
PHYSICAL CHEMISTRY
Composition: The ISO definition is 'a complex of zinc and maneb containing 20% of manganese and 2.55% of zinc, the salt present being stated (for instance mancozeb chloride)'. Form: Greyish-yellow powder. M.p.: Decomposes at 192-204C. V.p.: Negligible at 20C. S.g./density: 1.92. Solubility: In water 6.2 ppm (pH 7.5, 25C). Insoluble in most organic soents; dissoes in solutions of powerful chelating agents but cannot be recovered from them. Stability: Stable under normal, dry storage conditions. Slowly decomposed by heat and moisture. On hydrolysis (25C), DT50 20 d (pH 5), 17 h (pH 7), 34 h (pH 9). Mancozeb a.i. is unstable and the tech. not isolated; the formulated product is produced in continuous process. F.p.: 137.8C (Tag open cup).
APPLICATIONS
Biochemistry: Non-specific thiol reactant, inhibiting respiration.
Mode of action: Fungicide with protective action.

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